Selective and fast potentiometric sensors based on thiosemicarbazone with low detection limit for the determination of Cu2+ ions
   
Yazarlar (4)
Mehmet Emin Çakmak Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Oğuz ÖZBEK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Kıymet BERKİL AKAR Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Meliha Burcu GÜRDERE Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Microchemical Journal (Q1)
Dergi ISSN 0026-265X Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2025
Cilt / Sayı / Sayfa 209 / 1 / 1–7 DOI 10.1016/j.microc.2025.112894
Makale Linki https://doi.org/10.1016/j.microc.2025.112894
Özet
Thiosemicarbazones have been widely used as sensor materials in various analytical methods owing to their chemical structures. In this study, a thiosemicarbazone derivative molecule was synthesized, and its usability as a sensor material was then investigated. The newly developed sensors exhibited the highest potential against Cu2+ ions among various cationic species. The newly developed potentiometric sensor had a very low detection limit of 9.57 × 10−8 mol/L and Nernstian behavior of 28.7 ± 2.1 mV/decade over a wide concentration range of 1.0 × 10−7–1.0 × 10−1 mol/L. The sensors were shown to be economical and simple to prepare, to have good reproducibility, fast response time (<10 s), a wide pH working range (6.0–10.0), and to be suitable for on-site analysis. Analytical applications of the prepared sensors were performed by potentiometric titration and real sample applications. These new …
Anahtar Kelimeler
Copper(II) | Heavy metals | Ion selective electrodes | Potentiometry | Sensor
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 19
Scopus 17
Web of Science 17
Selective and fast potentiometric sensors based on thiosemicarbazone with low detection limit for the determination of Cu2+ ions

Paylaş