Design, Synthesis, and Thermal Characterization of N,N′-Dibutyl-1,6-Hexanediammonium Based Protic Ionic Liquids for Phase Change Energy Storage Applications
Yazarlar (2)
Prof. Dr. Derya KAHRAMAN DÖĞÜŞCÜ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Hüseyin AKBAŞ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayınlanan tam makale)
|
||
| Dergi Adı | Cumhuriyet Science Journal | ||
| Dergi ISSN | 2587-2680 | ||
| Dergi Tarandığı Indeksler | TR DİZİN | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2025 |
| Cilt / Sayı / Sayfa | 46 / 4 / 780–790 | DOI | 10.17776/csj.1733240 |
| Makale Linki | https://doi.org/10.17776/csj.1733240 | ||
| UAK Araştırma Alanları |
Fiziksel Kimya
|
||
| Özet |
| Protic ionic liquids (PILs) based on N, N′-Dibutyl-1, 6-hexanediammonium were successfully synthesized using lauric, palmitic, and myristic acids as anionic counterparts for thermal energy storage (TES) materials. The structural characteristics of the resulting PILs were characterized using FT-IR, 1H, and 13C NMR spectroscopy, which confirmed effective proton transfer and the formation of ionic bonds between the cationic and anionic species. Thermal properties, including thermal stability were examined using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The values for the latent heat of fusion were recorded as 69.73, 88.73, and 98.95 kJ/mol for PIL1, PIL2, and PIL3, respectively. Moreover, the synthesized PILs exhibit thermal stability up to around 463.15 K. The synthesized PILs showed strong thermal stability and appropriate phase change temperatures, indicating their suitability as PCMs for TES systems. This study provides insights into the design and development of novel PILs tailored for efficient and sustainable energy storage applications. |
| Anahtar Kelimeler |
| Protic ionic liquid | Phase change material | Fatty acid |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 1 |