Pyridine-based Anderson-type polyoxometalate hybrid: Synthesis, structural elucidation, and electrochemical and biological properties
Yazarlar (5)
Eyüp Akgün
Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Sabahattin Comertpay Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Jülide Nacaroğlu Ballı Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Mehmet Tümer Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2026 |
| Cilt / Sayı / Sayfa | 1360 / 1 / – | DOI | 10.1016/j.molstruc.2026.145522 |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0022286026002899 | ||
| Özet |
| The organic–inorganic hybrid species A(2-AMP), formed through salt formation of an Anderson-type polyoxometalate (POM) with 2-amino-4-methylpyridine (2-AMP), was synthesized and characterized, and its structural features, physicochemical behavior, and biological activity were established. Single-crystal X-ray diffraction confirmed the hybrid structure, revealing two half-POM units associated with three 2-AMP cations through hydrogen bonding and electrostatic interactions. FTIR, UV–Vis, and MALDI-TOF spectroscopies verified the integrity of the hybrid framework. Thermal analysis (TGA/DTA) demonstrated multi-step decomposition with stability up to 290 °C. Cyclic voltammetry showed multiple quasi-reversible redox processes (–1.5 to +1.5 V), indicating that the POM-centered electron-transfer behavior is modulated by the organic ligand. A(2-AMP) exhibited moderate cytotoxicity against H2452 … |
| Anahtar Kelimeler |
| Mesothelioma | Metallotherapeutics | Redox activity | X-ray structure of the POM hybrid |
Science Direct
Pyridine-based Anderson-type polyoxometalate hybrid: Synthesis, structural elucidation, and electrochemical and biological properties
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