Five novel dicyanidoaurate I based complexes exhibiting significant biological activities synthesis characterization and three crystal structures
Yazarlar (8)
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Yusuf YANAR
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Bilge Hilal ÇADIRCI
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Giresun Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | NEW JOURNAL OF CHEMISTRY |
| Dergi ISSN | 1144-0546 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2015 |
| Cilt No | 39 |
| Sayı | 10 |
| Sayfalar | 8136 / 8152 |
| DOI Numarası | 10.1039/c5nj01108f |
| Makale Linki | http://xlink.rsc.org/?DOI=C5NJ01108F |
| Özet |
| Five new cyanido-bridged coordination polymers having closed formulae [Ni(hydeten)Au2(CN)4] (C1), [Ni(hydeten)2Au2(CN)4]·H2O (C2), [Cu(hydeten)2Au2(CN)4]·CH3OH (C3), [Zn(hydeten)2 Au2(CN)4]·H2O (C4), and [Cd(hydeten)2Au2(CN)4]·H2O (C5) (hydeten: N-(2-hydroxyethyl)-ethylenediamine) have been prepared and characterized by elemental, thermal, FT-IR and XRD (C3, C4 and C5) measurement techniques. The anticancer, antibacterial and antifungal activities of the complexes are also investigated. The C3, C4 and C5 units according to XRD analyses are linked to each other via -CN-M(hydeten)-NC-Au(1)-CN-M(hydeten)-CN- chains (MII = Cu, Zn and Cd) and aurophilic interacted -Au(1)(CN)2-Au(2)(CN)2-Au(1)(CN)2-Au(2)(CN)2- zig-zag shaped chains along the a axis. C1, C2 and C4 show significant antifungal effects against several plant pathogenic fungi, while surprisingly C3 exhibits a considerable antibacterial effect against Gram negative E. coli. The studies of the antiproliferative activity on Hela, HT29 and C6 tumor cell lines indicated the anticancer potential of these complexes even at low doses. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 22 |
| SCOPUS | 24 |
| Google Scholar | 29 |