Strategic modifications in Aza-BODIPYs: The role of ferrocene and metal coordination in enhancing absorptivity and redox behavior
Yazarlar (1)
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q2)
Dergi ISSN 0022-2860 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 07-2025
Cilt / Sayı / Sayfa 1334 / 1 / 141801–0 DOI 10.1016/j.molstruc.2025.141801
Makale Linki https://doi.org/10.1016/j.molstruc.2025.141801
UAK Araştırma Alanları
Anorganik Kimya Analitik Kimya Fotoduyarlaştırıcı
Özet
Synthesis of chromophores with efficient near-infrared (NIR) light absorption, combined with high stability and photoactivity, remains a significant challenge in materials science. This study explores the enhancement of Azadipyrromethenes (ADPMs) through the incorporation of ferrocene, zinc, and boron. We provide synthesis and characterization data demonstrating that these modifications markedly improve the photophysical and electrochemical properties of ADPMs. The addition of metal centers increases molar absorptivity and alters redox behavior, while ferrocene substitution refines the electronic and steric properties. Structural analysis, including X-ray crystallography, reveals significant changes in bond angles and molecular conformation. The modified ADPMs exhibit enhanced absorption and stability, showcasing their potential for use in imaging, sensing, and phototherapy. This research underscores the …
Anahtar Kelimeler
Aza-BODIPY | Ferrocene | Metal complexation | Photophysical properties
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 1
Scopus 2
Google Scholar 2
Strategic modifications in Aza-BODIPYs: The role of ferrocene and metal coordination in enhancing absorptivity and redox behavior

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