Bimetallic nickel complexes supported by 2 5 bis phosphine 1 4 hydroquinonate ligands Structural electrochemical and theoretical investigations
Yazarlar (7)
Louis R. Pignotti
Michigan Technological University, Amerika Birleşik Devletleri
Michigan Technological University, Amerika Birleşik Devletleri
Rudy L. Luck
Michigan Technological University, Amerika Birleşik Devletleri
Michigan Technological University, Amerika Birleşik Devletleri
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
John D. Protasiewicz
Case Western Reserve University, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
Kevin E. Johnson
Pacific University, Amerika Birleşik Devletleri
Pacific University, Amerika Birleşik Devletleri
Lillian P. Nguyen
University Of Portland, Amerika Birleşik Devletleri
University Of Portland, Amerika Birleşik Devletleri
Eugenijus Urnezius
University Of Portland, Amerika Birleşik Devletleri
University Of Portland, Amerika Birleşik Devletleri
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Inorganica Chimica Acta | ||
| Dergi ISSN | 0020-1693 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2015 |
| Cilt / Sayı / Sayfa | 424 / 1 / 274–285 | DOI | 10.1016/j.ica.2014.08.049 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0020169314005490 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The coordination chemistries of several 2,5-bis(phosphine)-1,4-hydroquinones, (2,5-bis(PiPr2)-3,6-difluoro-1,4-hydroquinone (1a), 2,5-bis(PiPr2)-1,4-hydroquinone (1b), (2,5-bis(PPh2)-3,6-difluoro-1,4-hydroquinone (1c), and 2,5-bis(PPh2)-1,4-hydroquinone (1d)) were investigated. Reactions of these ligands 1a–d with excess (∼2.5) of bis(cyclopentadienide)nickel, and in case of 1a, with bis(pentamethylcyclopentadienide)nickel, resulted in the formation of bimetallic nickel complexes 2a–d and 3a, where both [P,O] chelating pockets of the ligands were occupied by CpNi or Cp∗Ni moieties, respectively. Cyclic voltammetric (CV) scans on complexes 2a–d contained a common feature of two reversible/quasi-reversible waves and one irreversible redox event. Complex [2a][PF6] was isolated by the oxidation of 2a with ferrocenium hexafluorophosphate. Spectroscopic, structural, and synthetic studies were carried out … |
| Anahtar Kelimeler |
| 1,4-Hydroquinone | Cyclic voltammetry | DFT calculation | Nickel dimers | Phosphines | X-ray crystal structures |
Science Direct
Bimetallic nickel complexes supported by 2 5 bis phosphine 1 4 hydroquinonate ligands Structural electrochemical and theoretical investigations
| Atıf Sayıları | |
| Web of Science | 6 |
| Scopus | 8 |
| Google Scholar | 8 |