Geminally Diaurated Aryls Bridged by Semirigid Phosphine Pillars Syntheses and Electronic Structure
Yazarlar (5)
Amberle R. Browne
Case Western Reserve University, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Bryce L. Anderson
Harvard Faculty Of Arts And Sciences, Amerika Birleşik Devletleri
Harvard Faculty Of Arts And Sciences, Amerika Birleşik Devletleri
Arnold L. Rheingold
University Of California, San Diego, Amerika Birleşik Devletleri
University Of California, San Diego, Amerika Birleşik Devletleri
Thomas G. Gray
Case Western Reserve University, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemistry A European Journal | ||
| Dergi ISSN | 0947-6539 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2014 |
| Cilt / Sayı / Sayfa | 20 / 52 / 17552–17564 | DOI | 10.1002/chem.201403444 |
| Makale Linki | http://doi.wiley.com/10.1002/chem.201403444 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| Geminally diaurated μ2‐aryl complexes have been prepared where gold(I) centers were bridged by the semirigid diphosphine ligands bis(2‐diphenylphosphinophenyl)ether (DPEphos) and 4,6‐bis(diphenylphosphanyl)dibenzo[b,d]furan (DBFphos). Diaurated complexes were synthesized in ligand redistribution reactions of the corresponding di‐gold dichlorides with di‐gold diaryls (six of them new) and silver(I) salts. Diaurated complexes were isolated as salts of the minimally coordinating anions SbF6− and ReO4−. Efforts to prepare salts of the tetraarylborate [B(3,5‐(CF3)2C6H3)4]− led to transmetalation from boron, with crystallization of the fluorinated aryl complex. The new complexes were characterized by multinuclear NMR, absorption and emission spectroscopies, 77 K emission lifetimes, and by combustion analysis; three are crystallographically characterized. Structures of geminally diaurated aryl ligands … |
| Anahtar Kelimeler |
| Aromaticity | Aurophilicity | Density functional calculations | Gold | Phosphine ligands |
| Atıf Sayıları | |
| Web of Science | 19 |
| Scopus | 19 |
| Google Scholar | 23 |