Comparison of 1 4 distyrylfluorene and 1 4 distyrylbenzene analogues synthesis structure electrochemistry and photophysics
Yazarlar (9)
Brynna J. Laughlin
Clemson University, Amerika Birleşik Devletleri
Tyler L. Duniho
Clemson University, Amerika Birleşik Devletleri
Samantha J. El Homsi
Clemson University, Amerika Birleşik Devletleri
Benjamin E. Levy
Clemson University, Amerika Birleşik Devletleri
Prof. Dr. Nihal DELİGÖNÜL Case Western Reserve University, Amerika Birleşik Devletleri
Joshua R. Gaffen
Case Western Reserve University, Amerika Birleşik Devletleri
John D. Protasiewicz
Case Western Reserve University, Amerika Birleşik Devletleri
Andrew G. Tennyson
Clemson University, Amerika Birleşik Devletleri
Rhett C. Smith
Clemson University, Amerika Birleşik Devletleri
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Organic and Biomolecular Chemistry
Dergi ISSN 1477-0520 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2013
Cilt / Sayı / Sayfa 11 / 33 / 5425–5434 DOI 10.1039/c3ob40580j
Makale Linki http://xlink.rsc.org/?DOI=c3ob40580j
UAK Araştırma Alanları
Anorganik Kimya
Özet
A series of nine 1,4-distyrylfluorene derivatives (2) functionalized with substituents of variable electron-donating or -accepting capabilities was synthesised. The photophysical properties of the molecules were investigated, including UV/vis absorption, photoluminescence emission, and fluorescence quantum yields. Photophysical properties of chromophores 2 were found to exhibit significant solvatochromic effects, especially in the Stokes shift and photoluminescence maxima. The electrochemical properties of series 2 were also assessed by cyclic voltammetry and differential pulse voltammetry. Results of photophysical and electrochemical analyses were further supported by DFT calculations (B3LYP/6-31G*) and single crystal X-ray diffraction on select molecules. The contributions of intermolecular π-stacking and hydrogen bonding to crystal packing are discussed. A series of nine 1,4-distyrylphenylene derivatives …
Anahtar Kelimeler
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 20
Scopus 20
Google Scholar 27
Comparison of 1 4 distyrylfluorene and 1 4 distyrylbenzene analogues synthesis structure electrochemistry and photophysics

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