Structural characterization and electrochemical properties of the 3 3 5 5 tetra tert butyl 4 4 diphenoquinone
Yazarlar (4)
Prof. Dr. Mehmet Tumer Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Mehmet Aslantas
Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Prof. Dr. Ertan Sahin Atatürk Üniversitesi, Türkiye
Prof. Dr. Nihal DELİGÖNÜL Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy | ||
| Dergi ISSN | 1386-1425 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2008 |
| Cilt / Sayı / Sayfa | 70 / 3 / 477–481 | DOI | 10.1016/j.saa.2007.07.039 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S1386142507004209 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| Crystals of the 3,3′-5,5′-tetra-tert-butyl-4,4′-diphenoquinone (TTBDQ) in the reaction mixture DCM/MeOH (1:1, v/v) were obtained as a result of CC coupling reaction of the sterically hindered phenol (2,6-di-tert-butylphenol, DTBP) using the binuclear Co(II) complexes. The oxidation product (TTBDQ), C28H40O2, crystallizes in the space group P1¯ with one-half molecule in the asymmetric unit and the other half generated by an inversion centre. The diphenoquinone moiety is planar within ±0.016(3)Å. The crystal structure is stabilized by intramolecular CH⋯O hydrogen bonds. The spectroscopic and electrochemical properties of the TTBDQ also have been studied. |
| Anahtar Kelimeler |
| Electrochemical | Oxidation product | X-ray |
Science Direct
Structural characterization and electrochemical properties of the 3 3 5 5 tetra tert butyl 4 4 diphenoquinone
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 9 |
| Scopus | 10 |
| Google Scholar | 12 |