Synthesis and Structural Studies of Pd II Zn II Architecture with N N Bis 2 hydroxyethyl ethylenediamine as Capping Ligand
Yazarlar (3)
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ahmet Karadağ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ertan Şahin Atatürk Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials | ||
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2013 |
| Cilt / Sayı / Sayfa | 23 / 4 / 1008–1014 | DOI | 10.1007/s10904-013-9861-6 |
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| A new compound of the composition [-{Zn-di-μ-bishydeten(O)-Zn}-μ-(CN)2Pd(CN)2] (1) was obtained from the reaction of PdCl2, bishydeten [N,N′-bis(2-hydroxyethyl)ethylenediamine], KCN and ZnCl2 in water/ethanol mixture. This dimeric polymer was characterized by IR spectroscopy and elemental analysis, and its thermal properties were studied by TG and DTG. In addition, the crystal structure was determined by single-crystal X-ray analysis. IR spectroscopy pointed out the existence of both terminal and bridged cyano ligands in the complex structure. When it comes to thermal analysis, the complex followed usual decomposition mechanism in which neutral ligands are decomposed first and then anionic ligands left the structure. Single crystal X-ray analysis revealed that 1 exhibited polymeric structure. An interesting feature of this complex is that ancillary bishydeten ligand acted as a bridge just like cyano … |
| Anahtar Kelimeler |
| Dimeric polymer | N,N′-bis(2-hydroxyethyl)ethylenediamine | Thermal analysis | Zinc complex |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 5 |
| Google Scholar | 4 |