5 Chloro 2 hydroxyaniline copper II coprecipitation system for preconcentration and separation of lead II and chromium III at trace levels      
Yazarlar (3)
Prof. Dr. Mustafa TÜZEN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Demirhan ÇITAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Mustafa Soylak
Erciyes Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Journal of Hazardous Materials
Dergi ISSN 0304-3894 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 10-2008
Cilt No 158
Sayı 1
Sayfalar 137 / 141
DOI Numarası 10.1016/j.jhazmat.2008.01.038
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0304389408001131
Özet
A separation-preconcentration procedure based on the coprecipitation of lead(II) and chromium(III) ions with copper(II)-5-chloro-2-hydroxyaniline system has been developed. Effects of pH, sample volume and interferences on the recovery of the metal ions were investigated. The detection limits corresponding to three times the standard deviation of the blank were found to be 2.72 μg L-1 for lead and 1.20 μg L-1 for chromium. The preconcentration factor is 50. The effectiveness of the present method was assessed by determining analyte metals in GBW 07309 stream sediment and NIST SRM 1633b coal fly ash certified reference materials. The method was successfully applied to the determination of trace lead and chromium in environmental samples. © 2008 Elsevier B.V. All rights reserved.
Anahtar Kelimeler
5-Chloro-2-hydroxyaniline | Coprecipitation | Environmental sample | Metal ion | Natural water