Poly(methyl methacrylate-co-ethylene glycole dimethacrylate-co-acrylamide)/N-Octadecane microparticles for thermal energy storage     
Yazarlar (3)
Doç. Dr. Derya KAHRAMAN DÖĞÜŞCÜ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yasemin Damlıoğlu
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Cemil ALKAN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Solar Energy Materials and Solar Cells
Dergi ISSN 0927-0248 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe
Basım Tarihi 05-2019
Cilt No 193
Sayı 1
Sayfalar 253 / 258
DOI Numarası 10.1016/j.solmat.2019.01.021
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0927024819300297
Özet
Microencapsulated phase change materials (MEPCMs) have been used for thermal regulation in different systems. MEPCMs are sometimes produced with functional groups to ease applications. This study focused on preparation, characterization, and determination of thermal properties of microencapsulated n-octadecane with poly(methyl methacrylate-co-ethylene glycol dimethacrylate-co-acrylamide) shell. P(MMA-co-EGDM-co-AAm)/ n-octadecane shell microcapsules were prepared with 0.5%, 1%, and 2% AAm contend to make the outer surface functional. Ethylene glycol dimethacrylate was used as uniformity agent. Amide functionality is the first time imported to MEPCMs in this study. The particle size, chemistry, photography, size distribution, thermal storage property and stability of MEPCMs were analyzed using Fourier transform infrared (FT-IR) spectroscopy, polarized optical microscopy (POM), particle sizer distribution (PSD), differential scanning calorimetry (DSC), and thermal gravimetric analysis (TGA) techniques respectively. The average melting and freezing temperatures of the MEPCMs were consistent with pristine core material, n-octadecane, as the average of latent heats of melting and crystallization were similar to the contend ratio in the recipe. Besides, produced microcapsules were found resistant to degradation up to 142 °C. The results indicated that the microcapsules with amide functionality have potential to be used as a TES material.
Anahtar Kelimeler
Microencapsulation | N-octadecane | Phase change material | Poly(methyl methacrylate-co-ethylene glycole dimethacrylate-co-acrylamide) | Thermal comfort